Szilard–Chalmers effect

E94910

The Szilard–Chalmers effect is a nuclear chemistry phenomenon in which atoms that undergo neutron capture and become radioactive are chemically separated from their original, non-activated atoms due to recoil-induced disruption of their chemical bonds.


Statements (39)
Predicate Object
instanceOf nuclear chemistry phenomenon
radiochemical effect
appliesTo gamma-activated atoms
neutron-activated atoms
cause recoil of nucleus after neutron capture
characteristic chemical behavior of activated atoms differs from bulk target
depends on recoil energy of product nucleus
depends on strength of chemical bonds in target compound
describes separation of activated atoms from non-activated atoms
discoveredBy Leó Szilárd NERFINISHED
Thomas A. Chalmers NERFINISHED
discoveryYear 1934
effect activated atoms leave original chemical compound
enrichment of radioactive isotopes in a different chemical fraction
field nuclear chemistry
radiochemistry
hasConsequence change in chemical form of product nuclide
spatial redistribution of radioactive atoms in a sample
involvesProcess chemical bond disruption
chemical separation
neutron capture
nuclear recoil
radioactivation
namedAfter Leó Szilárd NERFINISHED
Thomas A. Chalmers
occursIn liquid targets
solid targets
relatedTo hot atom chemistry
neutron activation analysis
recoil chemistry
requires irradiation with neutrons or other particles
theoreticalBasis conservation of momentum in nuclear reactions
interaction between nuclear processes and chemical bonds
usedFor isotope separation
production of carrier-free radioisotopes
radiotracer preparation
usedIn fundamental studies of chemical bonding under irradiation
radioisotope production for medicine
radioisotope production for research

Referenced by (1)
Subject (surface form when different) Predicate
Leo Szilard
knownFor

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