Clausius–Clapeyron relation

E303520

The Clausius–Clapeyron relation is a fundamental thermodynamic equation that describes how the pressure and temperature of a phase transition, such as boiling or condensation, are related.

All labels observed (2)

Label Occurrences
Clapeyron equation 2
Clausius–Clapeyron relation canonical 1

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Statements (48)

Predicate Object
instanceOf physical law
thermodynamic relation
appliesTo liquid–vapor equilibrium
phase transitions
solid–liquid equilibrium
solid–vapor equilibrium
approximateForm ln(P) = −L∕(R·T) + constant
assumes thermodynamic equilibrium between phases
category equation of state relations
phase equilibrium equations
derivedFrom Gibbs free energy equality of coexisting phases
first law of thermodynamics
second law of thermodynamics
describes dependence of phase equilibrium pressure on temperature
domain equilibrium thermodynamics
expresses slope of coexistence curve in P–T diagram
field thermodynamics
hasUnitContext SI units
hasVariable latent heat L
pressure P
specific volume v
temperature T
historicalPeriod 19th century
implies approximately 6–7 percent increase in saturation vapor pressure per kelvin near Earth surface temperatures
language mathematical physics notation
mathematicalForm dP/dT = L / (T · Δv)
namedAfter Émile Clapeyron
surface form: Benoît Paul Émile Clapeyron

Rudolf Clausius
relatedTo Gibbs–Duhem equation
Maxwell relations
vapor pressure curve
relatesQuantity latent heat
pressure
specific volume change
temperature
usedFor calculating saturation vapor pressure
climate science humidity scaling
cloud physics modeling
engineering thermodynamics calculations
estimating boiling point at different pressures
estimating condensation conditions
meteorology
usedIn boiler and condenser design
climate change precipitation projections
refrigeration cycle analysis
weather prediction models
validWhen latent heat is approximately constant over temperature range
vapor behaves approximately as ideal gas

How these facts were elicited

Referenced by (3)

Full triples — surface form annotated when it differs from this entity's canonical label.

Rudolf Clausius notableFor Clausius–Clapeyron relation
Émile Clapeyron notableWork Clausius–Clapeyron relation
this entity surface form: Clapeyron equation
Émile Clapeyron notableConcept Clausius–Clapeyron relation
this entity surface form: Clapeyron equation