Triple

T6788460
Position Surface form Disambiguated ID Type / Status
Subject Stokes shift E155871 entity
Predicate relatedTo P37 FINISHED
Object Franck–Condon principle E4700 NE FINISHED

How this triple was built (2 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Franck–Condon principle | Statement: [Stokes shift, relatedTo, Franck–Condon principle]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Franck–Condon principle
Context triple: [Stokes shift, relatedTo, Franck–Condon principle]
  • A. Franck–Condon principle chosen
    The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
  • B. Born–Oppenheimer approximation
    The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
  • C. Stokes shift
    Stokes shift is a phenomenon in spectroscopy where the wavelength of emitted light is longer (lower energy) than that of the absorbed light, commonly observed in fluorescence and phosphorescence.
  • D. Woodward–Hoffmann rules
    The Woodward–Hoffmann rules are fundamental principles in organic chemistry that predict the stereochemistry and feasibility of pericyclic reactions based on orbital symmetry considerations.
  • E. Herzberg–Teller approximation
    The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • F. None of above.
  • G. Unsure - the case is ambiguous/there is not enough information to decide.

Provenance (3 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69c6881770fc8190972b2906390380f5 completed March 27, 2026, 1:37 p.m.
NER Named-entity recognition batch_69c6d2aa2e0c8190b994261826ae001d completed March 27, 2026, 6:55 p.m.
NED1 Entity disambiguation (via context triple) batch_69c71a8998408190b741417ce6f21f55 completed March 28, 2026, 12:02 a.m.
Created at: March 27, 2026, 2:14 p.m.