Wigner–Eckart theorem
E98261
The Wigner–Eckart theorem is a fundamental result in quantum mechanics that factorizes matrix elements of tensor operators into a reduced matrix element and a purely geometric part given by Clebsch–Gordan coefficients, greatly simplifying angular momentum calculations.
All labels observed (2)
| Label | Occurrences |
|---|---|
| Wigner–Eckart theorem canonical | 7 |
| Wigner–Eckart factorization | 1 |
Statements (48)
| Predicate | Object |
|---|---|
| instanceOf |
result in angular momentum theory
ⓘ
theorem in quantum mechanics ⓘ |
| appliesTo |
angular momentum eigenstates
ⓘ
irreducible tensor operators ⓘ tensor operators ⓘ |
| assumes |
conservation of total angular momentum
ⓘ
tensor operator transforms irreducibly under rotations ⓘ |
| basedOn |
representation theory of SU(2)
ⓘ
rotational symmetry ⓘ |
| coreConcept | factorization of matrix elements ⓘ |
| dynamicPartGivenBy | reduced matrix element ⓘ |
| dynamicPartIndependentOf | magnetic quantum numbers ⓘ |
| field |
mathematical physics
ⓘ
quantum mechanics ⓘ theoretical physics ⓘ |
| generalizationOf | selection rules from rotational invariance ⓘ |
| geometricPartDependsOn | angular momentum quantum numbers ⓘ |
| geometricPartGivenBy | Clebsch–Gordan coefficients ⓘ |
| hasProperty |
independent of magnetic quantum numbers in reduced matrix element
ⓘ
separates dynamics from geometry ⓘ simplifies angular momentum calculations ⓘ uses selection rules from angular momentum algebra ⓘ |
| holdsFor | discrete angular momentum spectra ⓘ |
| holdsIn | Hilbert space of angular momentum eigenstates ⓘ |
| involves |
Clebsch–Gordan coefficients
ⓘ
Wigner–Eckart theorem self-linksurface differs ⓘ
surface form:
Wigner–Eckart factorization
angular momentum coupling ⓘ reduced matrix element ⓘ rotation group SU(2) ⓘ spherical tensor operators ⓘ |
| mathematicalFormulationUses |
group representation theory
ⓘ
spherical harmonics ⓘ |
| namedAfter |
Carl Eckart
ⓘ
Eugene Wigner ⓘ |
| relatedTo |
Clebsch–Gordan coefficients
ⓘ
surface form:
Clebsch–Gordan decomposition
Racah algebra ⓘ Clebsch–Gordan coefficients ⓘ
surface form:
Wigner 3-j symbols
Racah algebra ⓘ
surface form:
Wigner 6-j symbols
Wigner 9-j symbols ⓘ |
| statesThat | matrix elements of irreducible tensor operators factorize into a reduced matrix element and a purely geometric factor ⓘ |
| usedFor |
atomic spectroscopy calculations
ⓘ
deriving selection rules for transitions ⓘ evaluation of electromagnetic transition matrix elements ⓘ molecular spectroscopy ⓘ nuclear structure calculations ⓘ |
| usedIn |
many-body quantum systems with angular momentum coupling
ⓘ
quantum scattering theory ⓘ quantum theory of radiation ⓘ |
Referenced by (8)
Full triples — surface form annotated when it differs from this entity's canonical label.
this entity surface form:
Wigner–Eckart factorization