Nernst–Planck equation

E446184

The Nernst–Planck equation is a fundamental relation in electrochemistry that describes the flux of charged species under the combined influence of diffusion, electric fields, and, in extended forms, convection.

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Statements (53)

Predicate Object
instanceOf electrochemical equation
partial differential equation
phenomenological law
transport equation
appliesTo battery electrolytes
biological ion channels
charged species in electrolytes
electrochemical cells
fuel cell electrolytes
ionic transport through membranes
ions in solution
semiconductor charge carriers
assumes continuum description of electrolyte
dilute solution approximation in its simplest form
combinedWith Poisson equation NERFINISHED
continuity equation
describes coupled diffusion and migration of ions
flux of charged species
ion transport in electrolytes
mass transport in electrochemical systems
field biophysics
electrochemistry
membrane transport theory
physical chemistry
forms Poisson–Nernst–Planck equations NERFINISHED
generalizes Fick's first law of diffusion NERFINISHED
hasComponent Faraday constant NERFINISHED
absolute temperature
concentration gradient
diffusion coefficient
electric potential gradient
fluid velocity field
gas constant
valence of ion
hasForm flux equals sum of diffusive, migrative, and convective terms
includesProcess convection
diffusion
drift of charged particles
electromigration
migration in an electric field
namedAfter Max Planck NERFINISHED
Walther Nernst NERFINISHED
relates electrochemical potential to ion transport
ionic flux to concentration and potential gradients
usedIn modeling biological membranes
modeling corrosion systems
modeling electrode processes
modeling ion-selective membranes
modeling microfluidic electrokinetic flows
numerical simulations of electrochemical cells
usesConcept chemical potential
electric potential
electrochemical potential

Referenced by (1)

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Faraday constant appearsIn Nernst–Planck equation