London dispersion forces
E347195
London dispersion forces are weak, short-range intermolecular attractions arising from temporary fluctuations in electron density that induce instantaneous dipoles between atoms or molecules.
All labels observed (2)
| Label | Occurrences |
|---|---|
| London dispersion forces canonical | 2 |
| van der Waals forces | 1 |
Statements (48)
| Predicate | Object |
|---|---|
| instanceOf |
intermolecular force
ⓘ
physical interaction ⓘ van der Waals force ⓘ |
| actBetween |
atoms
ⓘ
molecules ⓘ noble gas atoms ⓘ nonpolar molecules ⓘ |
| alsoKnownAs |
London forces
ⓘ
dispersion forces ⓘ instantaneous dipole–induced dipole forces ⓘ |
| ariseFrom |
induced dipoles
ⓘ
instantaneous dipoles ⓘ temporary fluctuations in electron density ⓘ |
| categoryOf | induced dipole interactions ⓘ |
| contributeTo |
boiling points of substances
ⓘ
condensation of gases ⓘ liquefaction of noble gases ⓘ melting points of substances ⓘ solubility trends of nonpolar substances ⓘ surface tension of nonpolar liquids ⓘ viscosity of nonpolar liquids ⓘ |
| dependOn |
intermolecular distance
ⓘ
molecular polarizability ⓘ number of electrons ⓘ size of electron cloud ⓘ |
| energyDependenceOnDistance | approximately proportional to 1/r^6 ⓘ |
| existEvenIn | nonpolar substances ⓘ |
| explains |
existence of liquid and solid phases of noble gases
ⓘ
trend of boiling points in halogen series ⓘ |
| field |
materials science
ⓘ
molecular physics ⓘ physical chemistry ⓘ |
| increaseWith |
increasing molar mass
ⓘ
increasing surface area contact ⓘ |
| mathematicallyDescribedBy | attractive term in Lennard-Jones potential ⓘ |
| namedAfter | Fritz London ⓘ |
| presentIn | all atoms and molecules ⓘ |
| range | short-range ⓘ |
| relativeStrength | weak ⓘ |
| significantIn |
interactions between hydrocarbon chains
ⓘ
large nonpolar organic molecules ⓘ molecular crystals of nonpolar substances ⓘ |
| strongerThan | gravitational forces between molecules ⓘ |
| temperatureEffect | disrupted by increasing thermal motion ⓘ |
| weakerThan |
covalent bonds
ⓘ
hydrogen bonding ⓘ ionic bonds ⓘ ion–dipole interactions ⓘ |
Referenced by (3)
Full triples — surface form annotated when it differs from this entity's canonical label.
this entity surface form:
van der Waals forces