London dispersion forces

E347195

London dispersion forces are weak, short-range intermolecular attractions arising from temporary fluctuations in electron density that induce instantaneous dipoles between atoms or molecules.

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All labels observed (2)

Label Occurrences
London dispersion forces canonical 2
van der Waals forces 1

Statements (48)

Predicate Object
instanceOf intermolecular force
physical interaction
van der Waals force
actBetween atoms
molecules
noble gas atoms
nonpolar molecules
alsoKnownAs London forces
dispersion forces
instantaneous dipole–induced dipole forces
ariseFrom induced dipoles
instantaneous dipoles
temporary fluctuations in electron density
categoryOf induced dipole interactions
contributeTo boiling points of substances
condensation of gases
liquefaction of noble gases
melting points of substances
solubility trends of nonpolar substances
surface tension of nonpolar liquids
viscosity of nonpolar liquids
dependOn intermolecular distance
molecular polarizability
number of electrons
size of electron cloud
energyDependenceOnDistance approximately proportional to 1/r^6
existEvenIn nonpolar substances
explains existence of liquid and solid phases of noble gases
trend of boiling points in halogen series
field materials science
molecular physics
physical chemistry
increaseWith increasing molar mass
increasing surface area contact
mathematicallyDescribedBy attractive term in Lennard-Jones potential
namedAfter Fritz London
presentIn all atoms and molecules
range short-range
relativeStrength weak
significantIn interactions between hydrocarbon chains
large nonpolar organic molecules
molecular crystals of nonpolar substances
strongerThan gravitational forces between molecules
temperatureEffect disrupted by increasing thermal motion
weakerThan covalent bonds
hydrogen bonding
ionic bonds
ion–dipole interactions

Referenced by (3)

Full triples — surface form annotated when it differs from this entity's canonical label.

Fritz London notableFor London dispersion forces
Fritz knownFor London dispersion forces
subject surface form: Fritz London
theory of London dispersion forces componentOf London dispersion forces
this entity surface form: van der Waals forces