Kelvin–Planck statement of the second law of thermodynamics

E247922

The Kelvin–Planck statement of the second law of thermodynamics asserts that it is impossible to construct a cyclic heat engine that converts all absorbed heat from a single reservoir entirely into work without any other effect.

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Statements (43)

Predicate Object
instanceOf formulation of the second law of thermodynamics
thermodynamic law statement
appliesTo cyclic heat engines
macroscopic thermodynamic systems
assumes cyclic operation of the engine
existence of a thermal reservoir at constant temperature
category physical law
clarifiedBy statistical mechanics interpretation of entropy
constrains maximum efficiency of heat engines
describes impossibility of perfect heat-to-work conversion in a cyclic engine
limitations of heat engine efficiency
equivalentTo Clausius statement of the second law of thermodynamics under suitable assumptions
field statistical mechanics
thermodynamics
forbids cyclic device that converts heat from a single reservoir completely into work
perpetual motion machine of the second kind
hasConsequence heat engines must exchange heat with at least two reservoirs to produce work
no reversible engine can exceed the efficiency of a Carnot engine operating between the same two temperatures
historicalPeriod 19th century physics
implies directionality of natural thermodynamic processes
existence of waste heat in real heat engines
impossibility of 100 percent efficient heat engines
involvesConcept cyclic process
entropy
heat reservoir
thermal efficiency
work
logicalForm impossibility statement
namedAfter Max Planck
Lord Kelvin
surface form: William Thomson, 1st Baron Kelvin
partOf second law of thermodynamics
relatedTo Carnot cycle
surface form: Carnot heat engine

Carnot efficiency
surface form: Carnot theorem

Clausius statement of the second law of thermodynamics
perpetual motion machine of the second kind
states a cyclic heat engine must reject some heat to a lower-temperature reservoir if it produces work
no heat engine operating in a cycle can convert all the heat absorbed from a single reservoir into work
supports definition of thermodynamic temperature scale
taughtIn graduate statistical physics courses
undergraduate thermodynamics courses
usedIn design and analysis of power cycles
engineering thermodynamics
formulation of entropy increase principle

Referenced by (4)

Full triples — surface form annotated when it differs from this entity's canonical label.

Lord Kelvin knownFor Kelvin–Planck statement of the second law of thermodynamics
Carathéodory’s formulation of the second law of thermodynamics relatesTo Kelvin–Planck statement of the second law of thermodynamics
this entity surface form: Kelvin–Planck formulation of the second law
Clausius statement of the second law of thermodynamics relatedTo Kelvin–Planck statement of the second law of thermodynamics
Clausius statement of the second law of thermodynamics equivalentTo Kelvin–Planck statement of the second law of thermodynamics
this entity surface form: Kelvin–Planck statement of the second law of thermodynamics under suitable assumptions