Triple

T5781891
Position Surface form Disambiguated ID Type / Status
Subject Robert Robinson E127576 entity
Predicate knownFor P22 FINISHED
Object Robinson–Schöpf reaction
The Robinson–Schöpf reaction is a classic organic chemistry transformation that constructs polycyclic ring systems via a sequence involving Michael addition and intramolecular aldol condensation.
E545316 NE FINISHED

How this triple was built (4 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Robinson–Schöpf reaction | Statement: [Robert Robinson, knownFor, Robinson–Schöpf reaction]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Robinson–Schöpf reaction
Context triple: [Robert Robinson, knownFor, Robinson–Schöpf reaction]
  • A. Robinson annulation reaction
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • B. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • C. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • D. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • E. Buchwald–Hartwig amination
    The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Robinson–Schöpf reaction
Triple: [Robert Robinson, knownFor, Robinson–Schöpf reaction]
Generated description
The Robinson–Schöpf reaction is a classic organic chemistry transformation that constructs polycyclic ring systems via a sequence involving Michael addition and intramolecular aldol condensation.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Robinson–Schöpf reaction
Target entity description: The Robinson–Schöpf reaction is a classic organic chemistry transformation that constructs polycyclic ring systems via a sequence involving Michael addition and intramolecular aldol condensation.
  • A. Robinson annulation reaction chosen
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • B. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • C. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • D. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • E. Buchwald–Hartwig amination
    The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
  • F. None of above.

Provenance (5 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69c008361fa88190aefa4dc41b051e7f completed March 22, 2026, 3:18 p.m.
NER Named-entity recognition batch_69c02a17315881908aa12a830ba5f22b completed March 22, 2026, 5:42 p.m.
NED1 Entity disambiguation (via context triple) batch_69c0980d833481908e69a80a63bbe256 completed March 23, 2026, 1:31 a.m.
NEDg Description generation batch_69c098ba92408190b61b115540fce941 completed March 23, 2026, 1:34 a.m.
NED2 Entity disambiguation (via description) batch_69c099b4bc4481909e7cf6886e5ccbea completed March 23, 2026, 1:39 a.m.
Created at: March 22, 2026, 3:50 p.m.