Triple

T5628756
Position Surface form Disambiguated ID Type / Status
Subject Condon approximation E147782 entity
Predicate contrastedWith P278 FINISHED
Object Herzberg–Teller expansion of transition moment E27647 NE FINISHED

How this triple was built (2 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Herzberg–Teller expansion of transition moment | Statement: [Condon approximation, contrastedWith, Herzberg–Teller expansion of transition moment]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Herzberg–Teller expansion of transition moment
Context triple: [Condon approximation, contrastedWith, Herzberg–Teller expansion of transition moment]
  • A. Herzberg–Teller approximation chosen
    The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • B. Herzberg trilogy on molecular spectra
    The Herzberg trilogy on molecular spectra is a foundational multi-volume work that systematically presents the theory and experimental data of molecular spectroscopy, authored by Nobel laureate Gerhard Herzberg.
  • C. Rayleigh–Schrödinger perturbation theory
    Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
  • D. Born–Oppenheimer approximation
    The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
  • E. Longuet-Higgins theorem in molecular symmetry
    The Longuet-Higgins theorem in molecular symmetry is a fundamental result in theoretical chemistry that relates molecular symmetry properties to electronic state degeneracies and the occurrence of phenomena such as the Jahn–Teller effect.
  • F. None of above.
  • G. Unsure - the case is ambiguous/there is not enough information to decide.

Provenance (3 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69c00907bc8881909ed760d3ed73ef35 completed March 22, 2026, 3:21 p.m.
NER Named-entity recognition batch_69c0223b1e54819099fe5fc84ed17a88 completed March 22, 2026, 5:09 p.m.
NED1 Entity disambiguation (via context triple) batch_69c04d654c6c819087c1bcb4eb9530d0 completed March 22, 2026, 8:13 p.m.
Created at: March 22, 2026, 3:40 p.m.