Triple
T5628756
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Condon approximation |
E147782
|
entity |
| Predicate | contrastedWith |
P278
|
FINISHED |
| Object | Herzberg–Teller expansion of transition moment |
E27647
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Herzberg–Teller expansion of transition moment | Statement: [Condon approximation, contrastedWith, Herzberg–Teller expansion of transition moment]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Herzberg–Teller expansion of transition moment Context triple: [Condon approximation, contrastedWith, Herzberg–Teller expansion of transition moment]
-
A.
Herzberg–Teller approximation
chosen
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
B.
Herzberg trilogy on molecular spectra
The Herzberg trilogy on molecular spectra is a foundational multi-volume work that systematically presents the theory and experimental data of molecular spectroscopy, authored by Nobel laureate Gerhard Herzberg.
-
C.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
-
D.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
E.
Longuet-Higgins theorem in molecular symmetry
The Longuet-Higgins theorem in molecular symmetry is a fundamental result in theoretical chemistry that relates molecular symmetry properties to electronic state degeneracies and the occurrence of phenomena such as the Jahn–Teller effect.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69c00907bc8881909ed760d3ed73ef35 |
completed | March 22, 2026, 3:21 p.m. |
| NER | Named-entity recognition | batch_69c0223b1e54819099fe5fc84ed17a88 |
completed | March 22, 2026, 5:09 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69c04d654c6c819087c1bcb4eb9530d0 |
completed | March 22, 2026, 8:13 p.m. |
Created at: March 22, 2026, 3:40 p.m.