Triple
T5628743
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Condon approximation |
E147782
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object | Franck–Condon principle |
E4700
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Franck–Condon principle | Statement: [Condon approximation, relatedTo, Franck–Condon principle]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Franck–Condon principle Context triple: [Condon approximation, relatedTo, Franck–Condon principle]
-
A.
Franck–Condon principle
chosen
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
C.
Stokes shift
Stokes shift is a phenomenon in spectroscopy where the wavelength of emitted light is longer (lower energy) than that of the absorbed light, commonly observed in fluorescence and phosphorescence.
-
D.
Woodward–Hoffmann rules
The Woodward–Hoffmann rules are fundamental principles in organic chemistry that predict the stereochemistry and feasibility of pericyclic reactions based on orbital symmetry considerations.
-
E.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69c00907bc8881909ed760d3ed73ef35 |
completed | March 22, 2026, 3:21 p.m. |
| NER | Named-entity recognition | batch_69c0223b1e54819099fe5fc84ed17a88 |
completed | March 22, 2026, 5:09 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69c02882babc819093c987c745615865 |
completed | March 22, 2026, 5:36 p.m. |
Created at: March 22, 2026, 3:40 p.m.