Triple

T4741220
Position Surface form Disambiguated ID Type / Status
Subject E. J. Corey E105244 entity
Predicate developedReagent P73 FINISHED
Object Corey–Chaykovsky reagent
The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
E466670 NE FINISHED

How this triple was built (5 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Corey–Chaykovsky reagent | Statement: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Corey–Chaykovsky reagent
Context triple: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
  • A. Eschenmoser
    Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
  • B. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • C. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • D. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • E. Buchwald–Hartwig amination
    The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Corey–Chaykovsky reagent
Triple: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
Generated description
The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Corey–Chaykovsky reagent
Target entity description: The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
  • A. Eschenmoser
    Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
  • B. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • C. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • D. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • E. Buchwald–Hartwig amination
    The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
  • F. None of above. chosen
PD Predicate disambiguation gpt-5-mini-2025-08-07
Target predicate: developedReagent
Context triple: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
  • A. developed chosen
    Indicates that one entity created, designed, or brought another entity into a more advanced or complete state through effort or work.
  • B. developedInCase
    Indicates that something (such as a method, argument, or principle) was formulated, articulated, or established within the context of a particular case.
  • C. developedThrough
    Indicates that something came into existence, was created, or was brought to its current form by means of a specified process, method, or developmental pathway.
  • D. developedMethodUsedIn
    Indicates that a method created or developed by one entity is subsequently employed or applied in another entity, such as a study, project, or process.
  • E. developedAs
    Indicates that one entity was created, designed, or evolved specifically to function as or replace another entity.
  • F. None of above.

Provenance (6 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69bd43ef87a48190a5bc3600711aa032 completed March 20, 2026, 12:56 p.m.
NER Named-entity recognition batch_69bd64a5f3548190a6acf1dcfd64d11d completed March 20, 2026, 3:15 p.m.
NED1 Entity disambiguation (via context triple) batch_69be3a28ca648190a44d178826926812 completed March 21, 2026, 6:26 a.m.
NEDg Description generation batch_69be3c443c6881908d1a3de22ff1380b completed March 21, 2026, 6:35 a.m.
NED2 Entity disambiguation (via description) batch_69be3d0aa1d48190a2af91d251cb5561 completed March 21, 2026, 6:39 a.m.
PD Predicate disambiguation batch_69bd6221c3b881908604f35f8de6f16b completed March 20, 2026, 3:05 p.m.
Created at: March 20, 2026, 1:19 p.m.