Triple
T4741220
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | E. J. Corey |
E105244
|
entity |
| Predicate | developedReagent |
P73
|
FINISHED |
| Object |
Corey–Chaykovsky reagent
The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
|
E466670
|
NE FINISHED |
How this triple was built (5 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Corey–Chaykovsky reagent | Statement: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Corey–Chaykovsky reagent Context triple: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
-
A.
Eschenmoser
Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
-
B.
Eschenmoser sulfide contraction
Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
-
C.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
D.
Eschenmoser–Claisen rearrangement
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
E.
Buchwald–Hartwig amination
The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Corey–Chaykovsky reagent Triple: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
Generated description
The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Corey–Chaykovsky reagent Target entity description: The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
-
A.
Eschenmoser
Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
-
B.
Eschenmoser sulfide contraction
Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
-
C.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
D.
Eschenmoser–Claisen rearrangement
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
E.
Buchwald–Hartwig amination
The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
- F. None of above. chosen
PD
Predicate disambiguation
gpt-5-mini-2025-08-07
Target predicate: developedReagent Context triple: [E. J. Corey, developedReagent, Corey–Chaykovsky reagent]
-
A.
developed
chosen
Indicates that one entity created, designed, or brought another entity into a more advanced or complete state through effort or work.
-
B.
developedInCase
Indicates that something (such as a method, argument, or principle) was formulated, articulated, or established within the context of a particular case.
-
C.
developedThrough
Indicates that something came into existence, was created, or was brought to its current form by means of a specified process, method, or developmental pathway.
-
D.
developedMethodUsedIn
Indicates that a method created or developed by one entity is subsequently employed or applied in another entity, such as a study, project, or process.
-
E.
developedAs
Indicates that one entity was created, designed, or evolved specifically to function as or replace another entity.
- F. None of above.
Provenance (6 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69bd43ef87a48190a5bc3600711aa032 |
completed | March 20, 2026, 12:56 p.m. |
| NER | Named-entity recognition | batch_69bd64a5f3548190a6acf1dcfd64d11d |
completed | March 20, 2026, 3:15 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69be3a28ca648190a44d178826926812 |
completed | March 21, 2026, 6:26 a.m. |
| NEDg | Description generation | batch_69be3c443c6881908d1a3de22ff1380b |
completed | March 21, 2026, 6:35 a.m. |
| NED2 | Entity disambiguation (via description) | batch_69be3d0aa1d48190a2af91d251cb5561 |
completed | March 21, 2026, 6:39 a.m. |
| PD | Predicate disambiguation | batch_69bd6221c3b881908604f35f8de6f16b |
completed | March 20, 2026, 3:05 p.m. |
Created at: March 20, 2026, 1:19 p.m.