Triple

T22067512
Position Surface form Disambiguated ID Type / Status
Subject August Wilhelm von Hofmann E545313 entity
Predicate knownFor P22 FINISHED
Object Hofmann elimination NE NERFINISHED

How this triple was built (3 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Hofmann elimination | Statement: [August Wilhelm von Hofmann, knownFor, Hofmann elimination]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Hofmann elimination
Context triple: [August Wilhelm von Hofmann, knownFor, Hofmann elimination]
  • A. Claisen rearrangement
    The Claisen rearrangement is a pericyclic [3,3]-sigmatropic rearrangement in organic chemistry that converts allyl vinyl ethers (or related systems) into γ,δ-unsaturated carbonyl compounds with high stereospecificity.
  • B. Stork–Danheiser rearrangement
    The Stork–Danheiser rearrangement is an organic reaction that transforms certain allylic alcohol derivatives into rearranged carbonyl compounds via a sigmatropic shift, widely used in complex molecule synthesis.
  • C. Norrish reaction
    The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
  • D. Barton decarboxylation
    Barton decarboxylation is an organic reaction in which carboxylic acids are converted into radicals that lose carbon dioxide, enabling the formation of new carbon–hydrogen or carbon–carbon bonds.
  • E. Eschenmoser–Tanabe fragmentation
    The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Hofmann elimination
Target entity description: Hofmann elimination is an organic reaction in which quaternary ammonium hydroxides undergo thermal decomposition to yield alkenes, typically favoring the formation of the less substituted (Hofmann) alkene.
  • A. Claisen rearrangement
    The Claisen rearrangement is a pericyclic [3,3]-sigmatropic rearrangement in organic chemistry that converts allyl vinyl ethers (or related systems) into γ,δ-unsaturated carbonyl compounds with high stereospecificity.
  • B. Stork–Danheiser rearrangement
    The Stork–Danheiser rearrangement is an organic reaction that transforms certain allylic alcohol derivatives into rearranged carbonyl compounds via a sigmatropic shift, widely used in complex molecule synthesis.
  • C. Norrish reaction
    The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
  • D. Barton decarboxylation
    Barton decarboxylation is an organic reaction in which carboxylic acids are converted into radicals that lose carbon dioxide, enabling the formation of new carbon–hydrogen or carbon–carbon bonds.
  • E. Eschenmoser–Tanabe fragmentation
    The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
  • F. None of above. chosen

Provenance (2 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69e11e344dfc81909b1d88a7221329c7 completed April 16, 2026, 5:36 p.m.
NER Named-entity recognition batch_69f12884937c819095d3af69123fa2cb completed April 28, 2026, 9:37 p.m.
Created at: April 16, 2026, 8:27 p.m.