Triple
T22067512
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | August Wilhelm von Hofmann |
E545313
|
entity |
| Predicate | knownFor |
P22
|
FINISHED |
| Object | Hofmann elimination |
—
|
NE NERFINISHED |
How this triple was built (3 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Hofmann elimination | Statement: [August Wilhelm von Hofmann, knownFor, Hofmann elimination]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Hofmann elimination Context triple: [August Wilhelm von Hofmann, knownFor, Hofmann elimination]
-
A.
Claisen rearrangement
The Claisen rearrangement is a pericyclic [3,3]-sigmatropic rearrangement in organic chemistry that converts allyl vinyl ethers (or related systems) into γ,δ-unsaturated carbonyl compounds with high stereospecificity.
-
B.
Stork–Danheiser rearrangement
The Stork–Danheiser rearrangement is an organic reaction that transforms certain allylic alcohol derivatives into rearranged carbonyl compounds via a sigmatropic shift, widely used in complex molecule synthesis.
-
C.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
-
D.
Barton decarboxylation
Barton decarboxylation is an organic reaction in which carboxylic acids are converted into radicals that lose carbon dioxide, enabling the formation of new carbon–hydrogen or carbon–carbon bonds.
-
E.
Eschenmoser–Tanabe fragmentation
The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Hofmann elimination Target entity description: Hofmann elimination is an organic reaction in which quaternary ammonium hydroxides undergo thermal decomposition to yield alkenes, typically favoring the formation of the less substituted (Hofmann) alkene.
-
A.
Claisen rearrangement
The Claisen rearrangement is a pericyclic [3,3]-sigmatropic rearrangement in organic chemistry that converts allyl vinyl ethers (or related systems) into γ,δ-unsaturated carbonyl compounds with high stereospecificity.
-
B.
Stork–Danheiser rearrangement
The Stork–Danheiser rearrangement is an organic reaction that transforms certain allylic alcohol derivatives into rearranged carbonyl compounds via a sigmatropic shift, widely used in complex molecule synthesis.
-
C.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
-
D.
Barton decarboxylation
Barton decarboxylation is an organic reaction in which carboxylic acids are converted into radicals that lose carbon dioxide, enabling the formation of new carbon–hydrogen or carbon–carbon bonds.
-
E.
Eschenmoser–Tanabe fragmentation
The Eschenmoser–Tanabe fragmentation is an organic reaction that cleaves certain α,β-epoxy ketones or related substrates to form carbonyl compounds via a synthetically useful carbon–carbon bond fragmentation.
- F. None of above. chosen
Provenance (2 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69e11e344dfc81909b1d88a7221329c7 |
completed | April 16, 2026, 5:36 p.m. |
| NER | Named-entity recognition | batch_69f12884937c819095d3af69123fa2cb |
completed | April 28, 2026, 9:37 p.m. |
Created at: April 16, 2026, 8:27 p.m.