Triple

T18371317
Position Surface form Disambiguated ID Type / Status
Subject Butler–Volmer equation E446185 entity
Predicate relatedTo P37 FINISHED
Object Marcus theory of electron transfer NE NERFINISHED

How this triple was built (3 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Marcus theory of electron transfer | Statement: [Butler–Volmer equation, relatedTo, Marcus theory of electron transfer]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Marcus theory of electron transfer
Context triple: [Butler–Volmer equation, relatedTo, Marcus theory of electron transfer]
  • A. Taube mechanism in electron transfer
    The Taube mechanism in electron transfer is a foundational concept in inorganic chemistry that explains how electrons are transferred between metal complexes through ligand-bridged, often inner-sphere, pathways.
  • B. Kramers turnover theory
    Kramers turnover theory is a foundational concept in chemical physics that describes how reaction rates depend on friction or solvent viscosity, predicting a maximum (turnover) as friction varies.
  • C. Herzberg–Teller approximation
    The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • D. Grote–Hynes theory
    Grote–Hynes theory is a refinement of Kramers’ reaction-rate theory that incorporates frequency-dependent friction to more accurately describe barrier-crossing dynamics in condensed-phase chemical reactions.
  • E. Heitler–London theory of the chemical bond
    The Heitler–London theory of the chemical bond is an early quantum mechanical model that explains covalent bonding by treating it as the result of electron exchange and spin pairing between atoms.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Marcus theory of electron transfer
Target entity description: Marcus theory of electron transfer is a foundational framework in physical chemistry that explains how the rates of electron transfer reactions depend on the reorganization of molecular and solvent structures and the associated free energy changes.
  • A. Taube mechanism in electron transfer
    The Taube mechanism in electron transfer is a foundational concept in inorganic chemistry that explains how electrons are transferred between metal complexes through ligand-bridged, often inner-sphere, pathways.
  • B. Kramers turnover theory
    Kramers turnover theory is a foundational concept in chemical physics that describes how reaction rates depend on friction or solvent viscosity, predicting a maximum (turnover) as friction varies.
  • C. Herzberg–Teller approximation
    The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • D. Grote–Hynes theory
    Grote–Hynes theory is a refinement of Kramers’ reaction-rate theory that incorporates frequency-dependent friction to more accurately describe barrier-crossing dynamics in condensed-phase chemical reactions.
  • E. Heitler–London theory of the chemical bond
    The Heitler–London theory of the chemical bond is an early quantum mechanical model that explains covalent bonding by treating it as the result of electron exchange and spin pairing between atoms.
  • F. None of above. chosen

Provenance (2 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69d8b9f370b88190b1e5081c2c238e7f completed April 10, 2026, 8:50 a.m.
NER Named-entity recognition batch_69e5175324e48190a00572e15423feb7 completed April 19, 2026, 5:56 p.m.
Created at: April 10, 2026, 10:44 a.m.