Triple
T18371317
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Butler–Volmer equation |
E446185
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object | Marcus theory of electron transfer |
—
|
NE NERFINISHED |
How this triple was built (3 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Marcus theory of electron transfer | Statement: [Butler–Volmer equation, relatedTo, Marcus theory of electron transfer]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Marcus theory of electron transfer Context triple: [Butler–Volmer equation, relatedTo, Marcus theory of electron transfer]
-
A.
Taube mechanism in electron transfer
The Taube mechanism in electron transfer is a foundational concept in inorganic chemistry that explains how electrons are transferred between metal complexes through ligand-bridged, often inner-sphere, pathways.
-
B.
Kramers turnover theory
Kramers turnover theory is a foundational concept in chemical physics that describes how reaction rates depend on friction or solvent viscosity, predicting a maximum (turnover) as friction varies.
-
C.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
D.
Grote–Hynes theory
Grote–Hynes theory is a refinement of Kramers’ reaction-rate theory that incorporates frequency-dependent friction to more accurately describe barrier-crossing dynamics in condensed-phase chemical reactions.
-
E.
Heitler–London theory of the chemical bond
The Heitler–London theory of the chemical bond is an early quantum mechanical model that explains covalent bonding by treating it as the result of electron exchange and spin pairing between atoms.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Marcus theory of electron transfer Target entity description: Marcus theory of electron transfer is a foundational framework in physical chemistry that explains how the rates of electron transfer reactions depend on the reorganization of molecular and solvent structures and the associated free energy changes.
-
A.
Taube mechanism in electron transfer
The Taube mechanism in electron transfer is a foundational concept in inorganic chemistry that explains how electrons are transferred between metal complexes through ligand-bridged, often inner-sphere, pathways.
-
B.
Kramers turnover theory
Kramers turnover theory is a foundational concept in chemical physics that describes how reaction rates depend on friction or solvent viscosity, predicting a maximum (turnover) as friction varies.
-
C.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
D.
Grote–Hynes theory
Grote–Hynes theory is a refinement of Kramers’ reaction-rate theory that incorporates frequency-dependent friction to more accurately describe barrier-crossing dynamics in condensed-phase chemical reactions.
-
E.
Heitler–London theory of the chemical bond
The Heitler–London theory of the chemical bond is an early quantum mechanical model that explains covalent bonding by treating it as the result of electron exchange and spin pairing between atoms.
- F. None of above. chosen
Provenance (2 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d8b9f370b88190b1e5081c2c238e7f |
completed | April 10, 2026, 8:50 a.m. |
| NER | Named-entity recognition | batch_69e5175324e48190a00572e15423feb7 |
completed | April 19, 2026, 5:56 p.m. |
Created at: April 10, 2026, 10:44 a.m.