Triple
T17105391
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Kramers turnover theory |
E415084
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object | Kramers rate theory |
E415084
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Kramers rate theory | Statement: [Kramers turnover theory, relatedTo, Kramers rate theory]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Kramers rate theory Context triple: [Kramers turnover theory, relatedTo, Kramers rate theory]
-
A.
Kramers turnover theory
chosen
Kramers turnover theory is a foundational concept in chemical physics that describes how reaction rates depend on friction or solvent viscosity, predicting a maximum (turnover) as friction varies.
-
B.
Arrhenius equation for temperature dependence of reaction rates
The Arrhenius equation for temperature dependence of reaction rates is a fundamental formula in chemical kinetics that quantitatively relates a reaction’s rate constant to temperature and activation energy, explaining why reactions speed up as temperature increases.
-
C.
Eyring equation
The Eyring equation is a fundamental expression in chemical kinetics that relates reaction rates to temperature using transition state theory, providing insight into activation parameters such as enthalpy and entropy.
-
D.
Kirkwood approximation in statistical mechanics
The Kirkwood approximation in statistical mechanics is a method for approximating many-particle correlation functions by expressing higher-order correlations in terms of lower-order ones, simplifying the description of interacting particle systems.
-
E.
The Theory of Rate Processes (book, co-authored)
The Theory of Rate Processes is a foundational scientific book that systematically develops the theory of chemical reaction rates and laid the groundwork for modern transition state theory in physical chemistry.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d886cfc8e88190b05ba466edd35591 |
completed | April 10, 2026, 5:12 a.m. |
| NER | Named-entity recognition | batch_69e3dc2683fc81908af2df9012addecb |
completed | April 18, 2026, 7:31 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_6a01482766508190b2af157bf039000d |
completed | May 11, 2026, 3:08 a.m. |
Created at: April 10, 2026, 5:35 a.m.