Triple
T16803362
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Trost asymmetric allylic alkylation |
E408414
|
entity |
| Predicate | usesLigand |
P120395
|
FINISHED |
| Object |
Trost ligand
The Trost ligand is a chiral diphosphine ligand widely used in palladium-catalyzed asymmetric reactions, particularly for achieving high enantioselectivity in allylic alkylation.
|
E1233133
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Trost ligand | Statement: [Trost asymmetric allylic alkylation, usesLigand, Trost ligand]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Trost ligand Context triple: [Trost asymmetric allylic alkylation, usesLigand, Trost ligand]
-
A.
Wilkinson's catalyst
Wilkinson's catalyst is a homogeneous rhodium-based coordination complex widely used in organometallic chemistry for the catalytic hydrogenation of alkenes.
-
B.
Grubbs catalyst
Grubbs catalyst is a family of ruthenium-based organometallic complexes widely used to catalyze olefin metathesis reactions in organic and polymer chemistry.
-
C.
Eschenmoser
Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
-
D.
Corey–Chaykovsky reagent
The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
-
E.
Eschenmoser sulfide contraction
Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Trost ligand Triple: [Trost asymmetric allylic alkylation, usesLigand, Trost ligand]
Generated description
The Trost ligand is a chiral diphosphine ligand widely used in palladium-catalyzed asymmetric reactions, particularly for achieving high enantioselectivity in allylic alkylation.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Trost ligand Target entity description: The Trost ligand is a chiral diphosphine ligand widely used in palladium-catalyzed asymmetric reactions, particularly for achieving high enantioselectivity in allylic alkylation.
-
A.
Wilkinson's catalyst
Wilkinson's catalyst is a homogeneous rhodium-based coordination complex widely used in organometallic chemistry for the catalytic hydrogenation of alkenes.
-
B.
Grubbs catalyst
Grubbs catalyst is a family of ruthenium-based organometallic complexes widely used to catalyze olefin metathesis reactions in organic and polymer chemistry.
-
C.
Eschenmoser
Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
-
D.
Corey–Chaykovsky reagent
The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
-
E.
Eschenmoser sulfide contraction
Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d88393905081908d00a86b99996ac8 |
completed | April 10, 2026, 4:58 a.m. |
| NER | Named-entity recognition | batch_69e3b2ca46f88190b56e81d75012496c |
completed | April 18, 2026, 4:35 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_6a00ab16a13081908427d4f253cb14fa |
completed | May 10, 2026, 3:58 p.m. |
| NEDg | Description generation | batch_6a00ab8a416c819097ed3d6c915ac373 |
completed | May 10, 2026, 4 p.m. |
| NED2 | Entity disambiguation (via description) | batch_6a00ac301f188190ae25d5ae7a39eb34 |
completed | May 10, 2026, 4:02 p.m. |
Created at: April 10, 2026, 5:22 a.m.