Triple

T16803362
Position Surface form Disambiguated ID Type / Status
Subject Trost asymmetric allylic alkylation E408414 entity
Predicate usesLigand P120395 FINISHED
Object Trost ligand
The Trost ligand is a chiral diphosphine ligand widely used in palladium-catalyzed asymmetric reactions, particularly for achieving high enantioselectivity in allylic alkylation.
E1233133 NE FINISHED

How this triple was built (4 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Trost ligand | Statement: [Trost asymmetric allylic alkylation, usesLigand, Trost ligand]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Trost ligand
Context triple: [Trost asymmetric allylic alkylation, usesLigand, Trost ligand]
  • A. Wilkinson's catalyst
    Wilkinson's catalyst is a homogeneous rhodium-based coordination complex widely used in organometallic chemistry for the catalytic hydrogenation of alkenes.
  • B. Grubbs catalyst
    Grubbs catalyst is a family of ruthenium-based organometallic complexes widely used to catalyze olefin metathesis reactions in organic and polymer chemistry.
  • C. Eschenmoser
    Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
  • D. Corey–Chaykovsky reagent
    The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
  • E. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Trost ligand
Triple: [Trost asymmetric allylic alkylation, usesLigand, Trost ligand]
Generated description
The Trost ligand is a chiral diphosphine ligand widely used in palladium-catalyzed asymmetric reactions, particularly for achieving high enantioselectivity in allylic alkylation.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Trost ligand
Target entity description: The Trost ligand is a chiral diphosphine ligand widely used in palladium-catalyzed asymmetric reactions, particularly for achieving high enantioselectivity in allylic alkylation.
  • A. Wilkinson's catalyst
    Wilkinson's catalyst is a homogeneous rhodium-based coordination complex widely used in organometallic chemistry for the catalytic hydrogenation of alkenes.
  • B. Grubbs catalyst
    Grubbs catalyst is a family of ruthenium-based organometallic complexes widely used to catalyze olefin metathesis reactions in organic and polymer chemistry.
  • C. Eschenmoser
    Eschenmoser is a Swiss surname most notably associated with Albert Eschenmoser, a prominent organic chemist known for his pioneering work in the synthesis of complex natural products and studies on the origin of life.
  • D. Corey–Chaykovsky reagent
    The Corey–Chaykovsky reagent is an organosulfur ylide reagent widely used in organic synthesis to convert carbonyl compounds into epoxides and aziridines.
  • E. Eschenmoser sulfide contraction
    Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
  • F. None of above. chosen

Provenance (5 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69d88393905081908d00a86b99996ac8 completed April 10, 2026, 4:58 a.m.
NER Named-entity recognition batch_69e3b2ca46f88190b56e81d75012496c completed April 18, 2026, 4:35 p.m.
NED1 Entity disambiguation (via context triple) batch_6a00ab16a13081908427d4f253cb14fa completed May 10, 2026, 3:58 p.m.
NEDg Description generation batch_6a00ab8a416c819097ed3d6c915ac373 completed May 10, 2026, 4 p.m.
NED2 Entity disambiguation (via description) batch_6a00ac301f188190ae25d5ae7a39eb34 completed May 10, 2026, 4:02 p.m.
Created at: April 10, 2026, 5:22 a.m.