Triple
T16418979
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Eschenmoser sulfide contraction |
E398761
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object | Eschenmoser–Claisen rearrangement |
E398759
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Eschenmoser–Claisen rearrangement | Statement: [Eschenmoser sulfide contraction, relatedTo, Eschenmoser–Claisen rearrangement]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Eschenmoser–Claisen rearrangement Context triple: [Eschenmoser sulfide contraction, relatedTo, Eschenmoser–Claisen rearrangement]
-
A.
Eschenmoser–Claisen rearrangement
chosen
The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
-
B.
Claisen rearrangement
The Claisen rearrangement is a pericyclic [3,3]-sigmatropic rearrangement in organic chemistry that converts allyl vinyl ethers (or related systems) into γ,δ-unsaturated carbonyl compounds with high stereospecificity.
-
C.
Stork–Danheiser rearrangement
The Stork–Danheiser rearrangement is an organic reaction that transforms certain allylic alcohol derivatives into rearranged carbonyl compounds via a sigmatropic shift, widely used in complex molecule synthesis.
-
D.
Arbuzov rearrangement
The Arbuzov rearrangement is an organic reaction in which trialkyl or triaryl phosphites react with alkyl halides to form phosphonates, widely used in the synthesis of organophosphorus compounds.
-
E.
Overman rearrangement
The Overman rearrangement is an organic chemical reaction that converts allylic alcohol derivatives into allylic amines via a [3,3]-sigmatropic rearrangement of allylic trichloroacetimidates.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d87f2b9024819085c20e52de95d583 |
completed | April 10, 2026, 4:40 a.m. |
| NER | Named-entity recognition | batch_69e3287a3d348190831b12101d8449b6 |
completed | April 18, 2026, 6:45 a.m. |
| NED1 | Entity disambiguation (via context triple) | batch_6a006071a8ac8190b004a2861343960a |
completed | May 10, 2026, 10:39 a.m. |
Created at: April 10, 2026, 5:09 a.m.