Triple

T16418896
Position Surface form Disambiguated ID Type / Status
Subject Eschenmoser–Claisen rearrangement E398759 entity
Predicate reactionClass P69657 FINISHED
Object Claisen-type rearrangement E1211457 NE FINISHED

How this triple was built (3 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Claisen-type rearrangement | Statement: [Eschenmoser–Claisen rearrangement, reactionClass, Claisen-type rearrangement]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Claisen-type rearrangement
Context triple: [Eschenmoser–Claisen rearrangement, reactionClass, Claisen-type rearrangement]
  • A. Eschenmoser–Claisen rearrangement
    The Eschenmoser–Claisen rearrangement is a variant of the Claisen rearrangement in organic chemistry that converts allylic alcohols and amides into γ,δ-unsaturated carbonyl compounds via a [3,3]-sigmatropic rearrangement.
  • B. Stork–Danheiser rearrangement
    The Stork–Danheiser rearrangement is an organic reaction that transforms certain allylic alcohol derivatives into rearranged carbonyl compounds via a sigmatropic shift, widely used in complex molecule synthesis.
  • C. Arbuzov rearrangement
    The Arbuzov rearrangement is an organic reaction in which trialkyl or triaryl phosphites react with alkyl halides to form phosphonates, widely used in the synthesis of organophosphorus compounds.
  • D. Ireland–Claisen rearrangement chosen
    The Ireland–Claisen rearrangement is a variant of the Claisen rearrangement in which an ester enolate undergoes a [3,3]-sigmatropic rearrangement to form γ,δ-unsaturated carboxylic acids with high stereocontrol.
  • E. Overman rearrangement
    The Overman rearrangement is an organic chemical reaction that converts allylic alcohol derivatives into allylic amines via a [3,3]-sigmatropic rearrangement of allylic trichloroacetimidates.
  • F. None of above.
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
PD Predicate disambiguation gpt-5-mini-2025-08-07
Target predicate: reactionClass
Context triple: [Eschenmoser–Claisen rearrangement, reactionClass, Claisen-type rearrangement]
  • A. reactionType chosen
    Indicates the specific kind or category of reaction that occurs between entities or in response to an event or stimulus.
  • B. ringReaction
    Indicates that one entity performs or undergoes a reaction involving a chemical ring structure in relation to another entity.
  • C. reaction
    Indicates a chemical or physical process in which one set of substances or conditions transforms into another, often involving interaction, change, or response between entities.
  • D. netReaction
    Indicates the overall chemical transformation resulting from combining all individual reaction steps, showing only the net change between reactants and products.
  • E. sideReaction
    Indicates that one reaction occurs as an unintended or secondary process alongside a primary reaction.
  • F. None of above.

Provenance (4 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69d87f2b9024819085c20e52de95d583 completed April 10, 2026, 4:40 a.m.
NER Named-entity recognition batch_69e3287a3d348190831b12101d8449b6 completed April 18, 2026, 6:45 a.m.
NED1 Entity disambiguation (via context triple) batch_6a00457f60c081908f4e46993780ac09 completed May 10, 2026, 8:44 a.m.
PD Predicate disambiguation batch_69e226fe1dd08190865c181721f8c348 completed April 17, 2026, 12:26 p.m.
Created at: April 10, 2026, 5:09 a.m.