Triple
T14187047
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Suzuki coupling |
E351603
|
entity |
| Predicate | relatedReaction |
P82471
|
FINISHED |
| Object |
Heck reaction
The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
|
E1086298
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Heck reaction | Statement: [Suzuki coupling, relatedReaction, Heck reaction]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Heck reaction Context triple: [Suzuki coupling, relatedReaction, Heck reaction]
-
A.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
B.
Buchwald–Hartwig amination
The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
-
C.
Robinson annulation reaction
The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
-
D.
Diels–Alder reaction
The Diels–Alder reaction is a fundamental organic chemistry cycloaddition that forms six-membered rings by combining a conjugated diene with a dienophile in a single, stereospecific step.
-
E.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Heck reaction Triple: [Suzuki coupling, relatedReaction, Heck reaction]
Generated description
The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Heck reaction Target entity description: The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
-
A.
Barton reaction
The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
-
B.
Buchwald–Hartwig amination
The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
-
C.
Robinson annulation reaction
The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
-
D.
Diels–Alder reaction
The Diels–Alder reaction is a fundamental organic chemistry cycloaddition that forms six-membered rings by combining a conjugated diene with a dienophile in a single, stereospecific step.
-
E.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d8278834a08190b0f1784e58d7b99c |
completed | April 9, 2026, 10:26 p.m. |
| NER | Named-entity recognition | batch_69de61cd5778819092a03597bcdcc182 |
completed | April 14, 2026, 3:48 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69fd19433dc08190b4d2f1aef1b2d67d |
completed | May 7, 2026, 10:59 p.m. |
| NEDg | Description generation | batch_69fd1ad65b608190b325c82347a3d8b3 |
completed | May 7, 2026, 11:05 p.m. |
| NED2 | Entity disambiguation (via description) | batch_69fd1b68e8288190a9e9e3d855ed2719 |
completed | May 7, 2026, 11:08 p.m. |
Created at: April 10, 2026, 1:03 a.m.