Triple

T14187047
Position Surface form Disambiguated ID Type / Status
Subject Suzuki coupling E351603 entity
Predicate relatedReaction P82471 FINISHED
Object Heck reaction
The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
E1086298 NE FINISHED

How this triple was built (4 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Heck reaction | Statement: [Suzuki coupling, relatedReaction, Heck reaction]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Heck reaction
Context triple: [Suzuki coupling, relatedReaction, Heck reaction]
  • A. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • B. Buchwald–Hartwig amination
    The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
  • C. Robinson annulation reaction
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • D. Diels–Alder reaction
    The Diels–Alder reaction is a fundamental organic chemistry cycloaddition that forms six-membered rings by combining a conjugated diene with a dienophile in a single, stereospecific step.
  • E. Norrish reaction
    The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Heck reaction
Triple: [Suzuki coupling, relatedReaction, Heck reaction]
Generated description
The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Heck reaction
Target entity description: The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
  • A. Barton reaction
    The Barton reaction is an organic photochemical transformation that converts nitrite esters into δ-nitroso alcohols via intramolecular hydrogen abstraction and radical rearrangement.
  • B. Buchwald–Hartwig amination
    The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
  • C. Robinson annulation reaction
    The Robinson annulation reaction is a classic organic chemistry transformation that forms six-membered rings by combining a Michael addition with an intramolecular aldol condensation, widely used in the synthesis of complex cyclic molecules and natural products.
  • D. Diels–Alder reaction
    The Diels–Alder reaction is a fundamental organic chemistry cycloaddition that forms six-membered rings by combining a conjugated diene with a dienophile in a single, stereospecific step.
  • E. Norrish reaction
    The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
  • F. None of above. chosen

Provenance (5 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69d8278834a08190b0f1784e58d7b99c completed April 9, 2026, 10:26 p.m.
NER Named-entity recognition batch_69de61cd5778819092a03597bcdcc182 completed April 14, 2026, 3:48 p.m.
NED1 Entity disambiguation (via context triple) batch_69fd19433dc08190b4d2f1aef1b2d67d completed May 7, 2026, 10:59 p.m.
NEDg Description generation batch_69fd1ad65b608190b325c82347a3d8b3 completed May 7, 2026, 11:05 p.m.
NED2 Entity disambiguation (via description) batch_69fd1b68e8288190a9e9e3d855ed2719 completed May 7, 2026, 11:08 p.m.
Created at: April 10, 2026, 1:03 a.m.