Triple
T13308139
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Sharpless aminohydroxylation |
E316988
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object | Sharpless epoxidation |
E316986
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Sharpless epoxidation | Statement: [Sharpless aminohydroxylation, relatedTo, Sharpless epoxidation]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Sharpless epoxidation Context triple: [Sharpless aminohydroxylation, relatedTo, Sharpless epoxidation]
-
A.
Sharpless epoxidation
chosen
Sharpless epoxidation is a landmark asymmetric oxidation reaction in organic chemistry that enables the enantioselective conversion of allylic alcohols to epoxides using chiral catalysts.
-
B.
Shi epoxidation
Shi epoxidation is an asymmetric organocatalytic reaction that converts alkenes to chiral epoxides using a fructose-derived ketone catalyst and an oxidant such as oxone.
-
C.
Sharpless asymmetric dihydroxylation
Sharpless asymmetric dihydroxylation is a landmark chemical reaction that uses chiral catalysts to add two hydroxyl groups across an alkene with high enantioselectivity, revolutionizing asymmetric synthesis in organic chemistry.
-
D.
Corey–Kim oxidation
Corey–Kim oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones using N-chlorosuccinimide and dimethyl sulfide under mild conditions.
-
E.
Eschenmoser sulfide contraction
Eschenmoser sulfide contraction is an organic rearrangement reaction that converts certain sulfur-containing intermediates into carbonyl compounds, widely used in complex molecule and natural product synthesis.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d806b40ab4819094adf6c374f4811a |
completed | April 9, 2026, 8:06 p.m. |
| NER | Named-entity recognition | batch_69d990a8be108190bad0021f95ce3a93 |
completed | April 11, 2026, 12:07 a.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69f71f2810a881908b1ed0cc4fb9ac12 |
completed | May 3, 2026, 10:10 a.m. |
Created at: April 9, 2026, 9:29 p.m.