Triple
T13307982
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | K. Barry Sharpless |
E316985
|
entity |
| Predicate | knownFor |
P22
|
FINISHED |
| Object | Sharpless aminohydroxylation |
E316988
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Sharpless aminohydroxylation | Statement: [K. Barry Sharpless, knownFor, Sharpless aminohydroxylation]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Sharpless aminohydroxylation Context triple: [K. Barry Sharpless, knownFor, Sharpless aminohydroxylation]
-
A.
Sharpless aminohydroxylation
chosen
Sharpless aminohydroxylation is a stereoselective chemical reaction that converts alkenes into vicinal amino alcohols using a chiral catalyst, widely used in asymmetric synthesis.
-
B.
Sharpless epoxidation
Sharpless epoxidation is a landmark asymmetric oxidation reaction in organic chemistry that enables the enantioselective conversion of allylic alcohols to epoxides using chiral catalysts.
-
C.
Barton–McCombie deoxygenation
Barton–McCombie deoxygenation is an organic chemistry reaction that converts alcohols into the corresponding hydrocarbons via radical-mediated removal of the hydroxyl group.
-
D.
Sharpless asymmetric dihydroxylation
Sharpless asymmetric dihydroxylation is a landmark chemical reaction that uses chiral catalysts to add two hydroxyl groups across an alkene with high enantioselectivity, revolutionizing asymmetric synthesis in organic chemistry.
-
E.
Buchwald–Hartwig amination
The Buchwald–Hartwig amination is a palladium-catalyzed cross-coupling reaction that forms carbon–nitrogen bonds by coupling aryl (or vinyl) halides with amines, widely used in the synthesis of pharmaceuticals and fine chemicals.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d806b40ab4819094adf6c374f4811a |
completed | April 9, 2026, 8:06 p.m. |
| NER | Named-entity recognition | batch_69d990a8be108190bad0021f95ce3a93 |
completed | April 11, 2026, 12:07 a.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69f716e58cc48190afb46e8394227ab5 |
completed | May 3, 2026, 9:35 a.m. |
Created at: April 9, 2026, 9:29 p.m.