stereochemicalOutcome
P109438
predicate
Indicates the specific three-dimensional spatial arrangement of atoms or groups in the product(s) that results from a chemical reaction or transformation.
Observed surface forms (1)
- stereochemicalFeature ×3
Sample triples (17)
| Subject | Object |
|---|---|
| Barton reaction | can proceed with partial loss of stereochemistry at radical center ⓘ |
| Barton–McCombie deoxygenation | often leads to loss of stereochemistry at carbon center ⓘ |
| Brown hydroboration | retention of relative configuration ⓘ |
| Corey–Chaykovsky reagent | retention of configuration at carbonyl carbon ⓘ |
| Corey–Chaykovsky reagent | stereospecific epoxide formation ⓘ |
| Corey–Winter olefin synthesis | retention of relative configuration of the diol ⓘ |
| Corey–Winter olefin synthesis | stereospecific ⓘ |
| Diels–Alder reaction | suprafacial on diene via predicate surface "stereochemicalFeature" ⓘ |
| Diels–Alder reaction | suprafacial on dienophile via predicate surface "stereochemicalFeature" ⓘ |
| Eschenmoser–Claisen rearrangement | chirality transfer from allylic center ⓘ |
| Evans auxiliary-based asymmetric synthesis | products with high enantiomeric excess after auxiliary removal ⓘ |
| Overman rearrangement | allylic configuration can be transferred to nitrogen-bearing center via predicate surface "stereochemicalFeature" ⓘ |
| Overman rearrangement | stereospecific under appropriate conditions ⓘ |
| Robinson annulation reaction | creates stereocenters ⓘ |
| Sharpless asymmetric dihydroxylation | syn addition ⓘ |
| Sharpless epoxidation | asymmetric ⓘ |
| Sharpless epoxidation | enantioselective ⓘ |