van der Waals radius

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The van der Waals radius is a measure of the effective size of an atom or molecule that reflects how close it can approach another particle without forming a chemical bond.

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Statements (55)

Predicate Object
instanceOf atomic property
chemical property
intermolecular parameter
molecular property
alsoKnownAs vdW radius
approximatedBy half of the van der Waals contact distance between two identical atoms
characterizes closest approach without bonding
nonbonded contact distance
definedBy distance of closest approach between nonbonded atoms
dependsOn chemical environment
element type
molecular context
describes effective size of a molecule
effective size of an atom
differentFrom Bohr radius
atomic radius
covalent radius
ionic radius
metallic radius
importantFor understanding condensed phases
understanding crystal packing
understanding molecular recognition
measuredIn angstrom
picometer
namedAfter Johannes Diderik van der Waals NERFINISHED
relatedTo molecular volume
steric volume
van der Waals volume
relatesTo intermolecular interactions
nonbonded interactions
van der Waals forces
tabulatedIn chemical handbooks
force field parameter sets
usedIn Lennard-Jones potential NERFINISHED
Monte Carlo simulations
computational chemistry
crystallography
drug design
force field parameterization
interatomic potential functions
materials science
molecular dynamics simulations
molecular mechanics
molecular modeling
molecular surface calculations
packing coefficient calculations
protein–ligand docking
solvent-accessible surface area calculations
steric hindrance analysis
surface science
usedToEstimate excluded volume
molecular size
packing density
steric clashes in molecular structures
variesAcross periodic table

Referenced by (1)

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Johannes Diderik van der Waals notableConcept van der Waals radius