ESCA

E681654

ESCA (Electron Spectroscopy for Chemical Analysis) is an analytical technique based on X-ray photoelectron spectroscopy used to determine the elemental composition and chemical states of materials' surfaces.

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Predicate Object
instanceOf analytical technique
surface analysis technique
abbreviationOf Electron Spectroscopy for Chemical Analysis NERFINISHED
alsoKnownAs X-ray photoelectron spectroscopy NERFINISHED
analyzes material surfaces
basedOn photoelectric effect
belongsToField analytical chemistry
materials characterization
surface science
canDetect all elements except hydrogen and helium
commonlyUsedFor adhesion and coating studies
catalyst surface characterization
corrosion studies
polymer surface analysis
surface contamination analysis
thin film characterization
dataOutput binding energy vs intensity plot
photoelectron spectrum
determines chemical bonding environment
chemical states of elements
elemental composition of surfaces
oxidation states
developedFrom X-ray photoelectron spectroscopy principles
enables chemical state mapping of surfaces
depth profiling with sputtering
fullName Electron Spectroscopy for Chemical Analysis NERFINISHED
measures binding energy of core-level electrons
kinetic energy of emitted electrons
provides chemical shift information
quantitative elemental analysis
surface-sensitive information
quantificationMethod peak area analysis
sensitivity factor calibration
relatedTo Auger electron spectroscopy NERFINISHED
ultraviolet photoelectron spectroscopy
requires electron energy analyzer
monochromatic X-ray source
ultra-high vacuum chamber
ultra-high vacuum conditions
sensitivityRange atomic percent level
spectralFeatures Auger peaks
core-level peaks
plasmon loss features
shake-up satellites
surfaceSensitivityReason limited escape depth of photoelectrons
typicalAnalysisDepth a few nanometers
typicalEnergyRange 0–1500 eV binding energy
usesRadiationType X-rays

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Kai Siegbahn knownFor ESCA