Rydberg molecule

E679853

A Rydberg molecule is an exotic, weakly bound molecule formed when a highly excited Rydberg atom interacts with one or more nearby ground-state atoms, leading to extremely large bond lengths and unusual quantum properties.

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Statements (56)

Predicate Object
instanceOf exotic molecule
few-body quantum system
ultracold quantum system
weakly bound molecule
bindingMechanism Fermi pseudopotential interaction NERFINISHED
low-energy scattering of Rydberg electron from ground-state atom
bindingMechanism electron-neutral scattering
bondOrigin electron-neutral scattering resonance
shape resonance in electron-atom scattering
electronicState highly excited Rydberg state
existsIn Bose–Einstein condensates NERFINISHED
optical traps
ultracold atomic gases
firstExperimentalObservation 2009
firstObservedBy Chris H. Greene NERFINISHED
Johannes Deiglmayr NERFINISHED
Tilman Pfau NERFINISHED
firstObservedIn rubidium gas
hasComponent Rydberg atom NERFINISHED
ground-state atom
highly excited electron
hasProperty extremely large bond length
giant dipole moment
high principal quantum number
long-range interaction
non-classical bond
sensitivity to external fields
ultracold temperature regime
unusual vibrational structure
very weak binding energy
hasType butterfly Rydberg molecule NERFINISHED
p-type Rydberg molecule
polyatomic Rydberg molecule
s-type Rydberg molecule
trilobite Rydberg molecule
ultralong-range Rydberg molecule
lifetimeLimitedBy blackbody radiation
collisional decay
radiative decay of Rydberg state
potentialApplication precision measurements of scattering lengths
probing ultracold gases
quantum simulation
requiresCondition laser excitation to Rydberg state
ultracold atomic temperatures
ultrahigh vacuum
studiedIn atomic physics
molecular physics
quantum information science
quantum optics
theoreticalModel Fermi contact interaction model NERFINISHED
quantum defect theory
theorizedBy Enrico Fermi NERFINISHED
typicalBindingEnergy MHz scale
sub-MHz scale
typicalBondLength hundreds of nanometers
tens of nanometers

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Rydberg atoms relatedTo Rydberg molecule
subject surface form: Rydberg atom