Kramers–Heisenberg dispersion formula

E415083

The Kramers–Heisenberg dispersion formula is a fundamental quantum mechanical expression that describes how light is scattered by atoms and molecules, forming the basis for understanding phenomena such as Raman scattering and resonant inelastic X-ray scattering.

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Predicate Object
instanceOf dispersion formula
quantum mechanical formula
scattering theory formula
appliesTo elastic light scattering
inelastic light scattering
approximationOf full quantum electrodynamical scattering description
basisFor Raman scattering theory
nonresonant Raman scattering
nonresonant inelastic X-ray scattering descriptions
resonant Raman scattering
resonant inelastic X-ray scattering
characterizes line shapes in scattering spectra
polarization dependence of scattered light
resonant enhancement near electronic transitions
dependsOn final quantum state of the system
incident photon energy
initial quantum state of the system
scattered photon energy
sum over intermediate quantum states
transition matrix elements between states
describes frequency dependence of scattered radiation
quantum mechanical dispersion of radiation
scattering of light by atoms
scattering of light by molecules
field atomic physics
molecular physics
optics
quantum mechanics
historicalPeriod early quantum mechanics era
namedAfter Hendrik Anthony Kramers
Werner Heisenberg
relatedTo Compton effect
surface form: Compton scattering

Fermi golden rule
surface form: Fermi’s golden rule

Kramers–Kronig relations
Rayleigh scattering
Thomson scattering
optical theorem
relates incident photon frequency to scattered photon frequency
scattering amplitude to intermediate quantum states
scattering cross section to transition matrix elements
usedIn Raman effect
surface form: Raman spectroscopy

X-ray spectroscopy
nonlinear optics
resonant inelastic X-ray scattering experiments
spectroscopy
usesConcept Kramers–Kronig relations
energy denominators involving intermediate states
second-order time-dependent perturbation theory
transition dipole moments
virtual intermediate states

Referenced by (4)

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Hendrik Anthony Kramers notableWork Kramers–Heisenberg dispersion formula
Hendrik Anthony Kramers knownFor Kramers–Heisenberg dispersion formula
this entity surface form: Kramers–Heisenberg formula
Hendrik Anthony Kramers hasEponym Kramers–Heisenberg dispersion formula
this entity surface form: Kramers–Heisenberg formula
Kramers knownFor Kramers–Heisenberg dispersion formula
subject surface form: Hendrik Anthony Kramers