Ostwald ripening

E1026604

Ostwald ripening is a process in materials science where larger particles grow at the expense of smaller ones due to differences in solubility or chemical potential, leading to coarsening of the system over time.

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Statements (51)

Predicate Object
instanceOf materials science phenomenon
phase transformation mechanism
physical process
basedOn Gibbs–Thomson effect NERFINISHED
canBeReducedBy adding ripening inhibitors
lowering temperature
reducing solubility of dispersed phase
characterizedBy decrease in particle number density
dissolution of smaller particles
growth of larger particles
increase in average particle size
dependsOn interfacial energy
particle size distribution
solute diffusivity
temperature
volume fraction of dispersed phase
describedBy r^3 ∝ t growth law under diffusion control
drivenBy curvature-dependent solubility
differences in chemical potential
differences in solubility
surface energy minimization
field colloid science
materials science
physical chemistry
governedBy diffusion-controlled kinetics
interface-controlled kinetics
hasAlternativeName Lifshitz–Slyozov–Wagner coarsening NERFINISHED
coarsening
influencedBy elastic strain energy
particle-matrix coherency
presence of surfactants
solute supersaturation
modeledBy Lifshitz–Slyozov–Wagner theory NERFINISHED
namedAfter Wilhelm Ostwald NERFINISHED
occursDuring age hardening of alloys
emulsion destabilization
growth of quantum dots
precipitation in superalloys
sintering of ceramics
occursIn aerosols
emulsions
foams
liquid solutions
multiphase systems
nanoparticle dispersions
solid solutions
resultsIn change in catalytic activity
change in mechanical properties
change in optical properties
loss of fine dispersion
microstructural coarsening

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Wilhelm Ostwald notableWork Ostwald ripening